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Updated: Jun 1, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
5,6-Dihydr-oxy-1,10-phenanthrolin-1-ium chloride dihydrate
Xin-Yong Lin1, Sheng-Jiao Tang, Wen-Shi Wu
1College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, People's Republic of China.
Abstract:
The title compound, C(12)H(9)N(2)O(2) (+)·Cl(-)·2H(2)O, exhibits a layered structure which is stabilized by inter-molecular O-H⋯O, O-H⋯Cl(-) and N(+)-H⋯Cl(-) hydrogen bonds, and π-π inter-actions (centroid-centroid distances = 3.654 and 3.583 Å). The distances between the molecules are 3.371 and 3.294 Å.
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