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Updated: Jun 1, 2026
08:43
Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
4-Bromo-3-methyl-anilinium perchlorate
1Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Summary
The crystal structure of a novel compound reveals cations and anions linked by hydrogen bonds. These interactions form a unique two-dimensional network in the solid state.
Area of Science:
- Crystal Engineering
- Supramolecular Chemistry
- Solid-State Chemistry
Background:
- Understanding intermolecular forces is crucial for designing materials with specific properties.
- Hydrogen bonding plays a significant role in the self-assembly of molecular structures.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(7)H(9)BrN(+)·ClO(4) (-).
- To investigate the role of intermolecular interactions in the formation of extended networks.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed to determine the molecular and crystal structure.
- Analysis of intermolecular interactions, including hydrogen bonding, was performed.
Main Results:
- The crystal structure consists of cations (C(7)H(9)BrN(+)) and anions (ClO(4)(-)).
- Intermolecular N-H⋯O hydrogen bonds were identified between the cations and anions.
- These hydrogen bonds facilitate the formation of a two-dimensional network structure parallel to the ab plane.
Conclusions:
- The study successfully characterized the crystal structure of the title compound.
- The observed two-dimensional network highlights the importance of hydrogen bonding in supramolecular assembly.
- This structural motif could serve as a basis for designing novel functional materials.
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