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Updated: Jun 1, 2026
09:45
Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Published on: April 27, 2017
2-Methyl-sulfanyl-4-(3-pyrid-yl)pyrimidine
Ren-Jun Du1, Jian-Qiang Wang, Sheng Bi
1College of Science, Nanjing University of Technology, Xinmofan Road No. 5 Nanjing, Nanjing 210009, People's Republic of China.
Summary
The crystal structure of C(10)H(9)N(3)S reveals a slight dihedral angle between aromatic rings. Molecules are linked by C-H⋯N interactions, forming crystal chains.
Area of Science:
- Crystallography
- Chemical Physics
Background:
- Understanding molecular interactions is key in crystal engineering.
- Aromatic ring orientations influence material properties.
Purpose of the Study:
- To characterize the crystal structure of the title compound C(10)H(9)N(3)S.
- To investigate intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed.
- Analysis of the crystal packing and hydrogen bonding was performed.
Main Results:
- The dihedral angle between the aromatic rings in C(10)H(9)N(3)S was determined to be 8.09(14)°.
- A significant C-H⋯N interaction was identified, linking molecules into chains.
- The crystal structure exhibits a one-dimensional chain motif.
Conclusions:
- The C-H⋯N interaction plays a crucial role in the self-assembly of C(10)H(9)N(3)S molecules.
- The observed crystal packing provides insights into the solid-state behavior of this compound.
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