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Updated: Jun 1, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Poly[[aqua-(μ-4,4'-bipyridine-κN:N')(μ(3)-2-nitro-5-sulfonatobenzoato-κO:O:O)copper(II)] 4,4'-bipyridine hemisolvate]
1Department of Chemistry, Baicheng Normal College, Baicheng 137000, People's Republic of China.
Abstract:
In the title compound, [Cu(C(7)H(3)NO(7)S)(C(10)H(8)N(2))(H(2)O)]·0.5C(10)H(8)N(2), the Cu(II) atom is six-coordinated by two N atoms from two different bipyridine (bipy) ligands, one sulfonate O atom and two carboxyl-ate O atoms from three 2-nitro-5-sulfonatobenzoate ligands and one water O atom in a distorted octa-hedral geometry. The bipy solvent mol-ecule lies on an inversion center. The Cu(II) atoms are linked by the bipy ligands, forming one-dimensional chains, which are connected by the 2-nitro-5-sulfonatobenzoate ligands into a two-dimensional layer-like network. The two-dimensional structure is extended by O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensional supra-molecular network.
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