Related Experiment Video
Updated: Jun 1, 2026
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
(2,2'-Bipyridine-κN,N')dibromido-palladium(II) dichloro-methane solvate
1School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
Abstract:
In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2'-bipyridine ligand and two bromide ions. The compound displays intra-molecular C-H⋯Br hydrogen bonds and pairs of complex mol-ecules are assembled by inter-molecular C-H⋯Br hydrogen bonds. These pairs are connected by additional C-H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Inter-molecular π-π inter-actions between the pyridine rings of the ligand are also present, the shortest centroid-centroid distance being 4.090 (9) Å.
More Related Videos
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
11:44Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
08:46Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Related Concept Videos
03:35Hybridization of Atomic Orbitals II
03:24Hybridization of Atomic Orbitals I
01:14Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene