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Updated: Jun 1, 2026

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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
{2-[Bis(3-methyl-1H-indol-2-yl)meth-yl]phenolato-κO}dimeth-yl(tetra-hydro-furan-κO)aluminium(III)
Abstract:
The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl-aluminum in tetra-hydro-furan. The ligands adopt a distorted tetra-hedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present.
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