Related Experiment Video
Updated: Jun 1, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
[(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl-phospho-rane}(penta-fluoro-phenyl-κC)gold(I) diethyl
Christoph E Strasser1, Karolien Coetzee, Stephanie Cronje
1Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa.
Abstract:
The metal atom in the title ylid-gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C-Au-C = 174.1 (2)°]. The mol-ecule has a short intra-molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol-ecules are linked by an Au⋯H(ylid) inter-action (Au⋯H = 3.14 Å).
More Related Videos
10:42Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
11:44Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Related Concept Videos
Predicting Molecular Geometry
Crown Ethers
Hybridization of Atomic Orbitals II
Acidity and Basicity of Alcohols and Phenols
EDTA: Chemistry and Properties
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group with both...