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Updated: Jun 1, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Bis[μ-1-(2-pyridylmeth-yl)-1H-benzo-triazole]disilver(I) bis-(perchlorate)
Abstract:
In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth-yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intra-molecular Ag⋯Ag separation of 4.479 (2) Å. Inter-molecular C-H⋯O hydrogen-bonding inter-actions, involving uncoordinated ClO(4) (-) ions, link the binuclear units, forming a two-dimensional network parallel to (10).
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