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Updated: Jun 1, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Poly[[[bis-(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κN:N] dihydrate]
Yi-Fang Deng1, Man-Sheng Chen, Dai-Zhi Kuang
1Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, People's Republic of China.
Abstract:
In the title linear coordination polymer, {[Cu(C(2)H(3)O(2))(2)(C(12)H(10)N(4))]·2H(2)O}(n), the Cu(II) atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxyl-ate O atoms from two acetate ligands in a square-planar geometry. The Cu atoms are linked by the dib ligands, forming an extended chain. These chains are linked by O-H⋯O hydrogen bonds into a three-dimensional supra-molecular network. The Cu(II) atom lies on a center of inversion.
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