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Updated: Jun 1, 2026

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
Published on: January 19, 2016
2-(Methoxy-meth-yl)adamantan-2-yl 2-methyl-acrylate
Qingwei Meng1, Yueqing Li, Pingping Chen
1State Key Laboratory of Fine Chemicals, Dalian Unversity of Technology, PO Box 90, Zhongshan Road 158, Dalian 116012, People's Republic of China.
This study details a cage-type molecule, C(16)H(24)O(3), highlighting its unique photochemical properties. The compound forms a 3D network through non-classical C-H⋯O hydrogen bonding.
Area of Science:
- Organic Chemistry
- Crystallography
- Photochemistry
Background:
- Cage-type molecular structures are of interest for their unique properties.
- Understanding intermolecular interactions is crucial for materials science.
Purpose of the Study:
- To characterize the molecular structure and photochemical properties of C(16)H(24)O(3).
- To investigate the role of intermolecular hydrogen bonding in the compound's network formation.
Main Methods:
- X-ray crystallography was used to determine the molecular structure.
- Analysis of intermolecular interactions, specifically C-H⋯O hydrogen bonds.
Main Results:
- The title compound, C(16)H(24)O(3), possesses a distinct cage-type molecular architecture.
- Non-classical intermolecular C-H⋯O hydrogen bonds were identified.
- These interactions facilitate the formation of a three-dimensional molecular network.
Conclusions:
- The cage-type structure of C(16)H(24)O(3) is stabilized by non-classical hydrogen bonding.
- The observed network structure may influence the compound's photochemical behavior.
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