Related Experiment Video

Updated: Jun 1, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach

Published on: June 10, 2021

3-Amino-carbonyl-pyridinium difluoro-acetate at 123 K

Julie Bardin, Alastair J Florence, Jean-Baptiste Arlin

Acta Crystallographica. Section E, Structure Reports Online

|May 18, 2011

Abstract:

In the crystal of the title compound, C(6)H(7)N(2)O(+)·C(2)HF(2)O(2) (-), the cation adopts a catemeric N-H⋯O hydrogen-bonded chain motif involving the carboxamide group, with two further N-H⋯O hydrogen bonds connecting the cations to adjacent difluoro-acetate anions via the carboxamide and pyridinium N atoms. The carboxamide group of the nicotinamidium ion is twisted by 32.3 (6)° from the pyridine ring plane. A number of C-H⋯O and C-H⋯F interactions consolidate the packing.

More Related Videos

Direct Detection of the Acetate-forming Activity of the Enzyme Acetate Kinase

Direct Detection of the Acetate-forming Activity of the Enzyme Acetate Kinase

Published on: December 19, 2011

Measuring the Spin-Lattice Relaxation Magnetic Field Dependence of Hyperpolarized [1-13C]pyruvate

Measuring the Spin-Lattice Relaxation Magnetic Field Dependence of Hyperpolarized [1-¹³C]pyruvate

Published on: September 13, 2019

Related Concept Videos

¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)

¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)

When proton-coupled carbon-13 spectra are simplified by a broadband proton decoupling technique, structural information about the coupled protons is lost. Distortionless enhancement by polarization transfer (DEPT) is a technique that provides information on the number of hydrogens attached to each carbon in a molecule. While the DEPT experiment utilizes complex pulse sequences, the pulse delay and flip angle are specifically manipulated. The resulting signals have different phases depending on...

Articles linked to this work by shared authors, journal, and citation graph.

3D electron diffraction shows structural flexibility in rare Zn(II) paddlewheel-based metal-organic polyhedra.

Chemical communications (Cambridge, England)·2026

Stabilisation of Al(III) organometallics using a fluorenyl-tethered N-heterocyclic carbene ligand.

Dalton transactions (Cambridge, England : 2003)·2026

A family of tetranuclear Ln(III) complexes based on a terphenyl dicarboxylic acid ligand: synthesis, structure, and photophysical properties.

Dalton transactions (Cambridge, England : 2003)·2026

Salt forms of the monoazo dye Mordant Orange 1.

Acta crystallographica. Section C, Structural chemistry·2026

Predicting the viability of pharmaceutical formulations for continuous direct compression using machine learning approaches.

International journal of pharmaceutics·2026

Comparisons and Contrasts in a Complete Set of Alkali Metal Cumyl Structures.

Inorganic chemistry·2026

See all related articles