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4-Bromo-N-(diisopropoxyphosphor-yl)benzamide
The crystal structure of C(13)H(19)BrNO(4)P features intermolecular hydrogen bonds. These bonds link molecules into dimers, which then stack along the c-axis via other interactions.
Area of Science:
- Crystal structure analysis
- Supramolecular chemistry
- Organic chemistry
Background:
- Understanding intermolecular forces is crucial for predicting material properties.
- Hydrogen bonding and C-H interactions play significant roles in crystal packing.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(13)H(19)BrNO(4)P.
- To identify and characterize the intermolecular interactions stabilizing the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of hydrogen bonding (N-H⋯O) and other non-covalent interactions (C-H⋯O, C-H⋯π) was performed.
Main Results:
- The crystal structure is stabilized by intermolecular N-H⋯O hydrogen bonds, forming centrosymmetric dimers.
- These dimers are further organized into stacks along the c-axis through C-H⋯O and C-H⋯π interactions.
Conclusions:
- The study reveals the key intermolecular interactions governing the crystal packing of C(13)H(19)BrNO(4)P.
- The identified hydrogen bonding and stacking interactions provide insights into the supramolecular assembly of this compound.
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