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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
2-Methyl-6-[2-(trifluoro-meth-yl)phenyl-imino-meth-yl]phenol
Hasan Tanak1, Metin Yavuz, Orhan Büyükgüngör
1Department of Physics, Faculty of Arts & Science, Ondokuz Mayıs University, TR-55139 Kurupelit-Samsun, Turkey.
Abstract:
The title compound, C(15)H(12)F(3)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 38.79 (5)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring. In addition, there is an intra-molecular short C-H⋯F contact.
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