Related Experiment Video
Updated: Jun 1, 2026

09:45
Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Published on: April 27, 2017
[(Z)-N-Isopropyl-O-methyl-thio-carbamato-κS](tri-p-tolyl-phosphine-κP)gold(I)
Abstract:
In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol-ecules comprise the asymmetric unit, and these are connected by an aurophilic inter-action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31 (5) and 176.45 (5)°] ascribed to an intra-molecular Au⋯O contact in each case [2.974 (4) and 3.027 (4) Å].

