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The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Chlorido(dimethyl sulfoxide-κO)triphenyl-tin(IV)
Summary
This study details the crystal structure of a tin(IV) compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], revealing its distorted trigonal-bipyramidal geometry. Intermolecular interactions like C-H⋯Cl hydrogen bonds and π-π stacking influence its crystal packing.
Area of Science:
- Organometallic Chemistry
- Crystallography
- Supramolecular Chemistry
Background:
- Organotin compounds exhibit diverse coordination geometries and bonding.
- Understanding intermolecular forces is crucial for predicting material properties.
Purpose of the Study:
- To characterize the crystal structure of the title tin(IV) compound.
- To investigate the intermolecular interactions governing crystal packing.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed.
- The coordination geometry around the tin(IV) center was determined.
- Intermolecular interactions were identified and analyzed.
Main Results:
- The tin(IV) atom displays a distorted trigonal-bipyramidal coordination.
- The coordination sphere includes three phenyl groups, a chloride ion, and a dimethyl sulfoxide molecule.
- Crystal packing is influenced by intermolecular C-H⋯Cl hydrogen bonds, C-H⋯π, and π-π interactions.
Conclusions:
- The study provides a detailed structural description of the tin(IV) complex.
- Intermolecular forces play a significant role in the self-assembly of the compound in the solid state.
- The findings contribute to the understanding of organotin chemistry and crystal engineering.
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