[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I)
Abstract:
In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au⋯O = 2.959 (4) Å].
More Related Videos
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
08:46Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Related Concept Videos
α-Bromination of Carboxylic Acids: Hell–Volhard–Zelinski Reaction
Preparation of Nitriles
Carboxylic Acids to Acid Chlorides
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3
Carbocations
