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Updated: Jun 1, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
4,4'-Bis(dimethyl-amino)benzhydryl phenyl sulfone
Mahiuddin Baidya1, Herbert Mayr, Peter Mayer
1Ludwig-Maximilians-Universität, Department, Butenandtstrasse 5-13, 81377 München, Germany.
Abstract:
In the title compound, C(23)H(26)N(2)O(2)S, the sulfur-bound phenyl group is aligned approximately parallel to one of the two rings of the benzhydryl group, making a dihedral angle of 1.15 (9)°. The other forms a dihedral angle of 59.20 (9)° with the phenyl group bound to the S atom. In the crystal, mol-ecules are linked into strands along [100] by weak C-H⋯O contacts. Weak C-H⋯π inter-actions are also observed.
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