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Updated: Jun 1, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
3-[1-(3,4-Dichloro-phen-yl)eth-yl]-1,3-thia-zinane-2-thione
Abstract:
In the title compound, C(12)H(13)Cl(2)NS(2), the thia-zinane ring adopts a half-boat conformation. An intra-molecular C-H⋯S hydrogen bond is observed. In the crystal structure, centrosymmetrically related mol-ecules inter-act through an aromatic π-π stacking inter-actions, with a centroid-centroid separation of 3.790 (2) Å.
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