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Related Concept Videos

Minerals01:26

Minerals

Minerals are essential nutrients that the human body needs in small amounts to work properly. They play a vital role in many bodily functions, such as building strong bones and transmitting nerve impulses. Some minerals are needed for hormone production or to maintain a normal heartbeat. Major minerals include calcium, phosphorus, potassium, sulfur, sodium, chlorine, and magnesium, while trace minerals include iron, manganese, copper, iodine, zinc, cobalt, fluoride, and selenium.

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Synchrotron X-ray Microdiffraction and Fluorescence Imaging of Mineral and Rock Samples
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Synchrotron X-ray Microdiffraction and Fluorescence Imaging of Mineral and Rock Samples

Published on: June 19, 2018

Scheelite-type NaEr(MoO(4))(2).

Dan Zhao, Feifei Li, Wendan Cheng

    Acta Crystallographica. Section E, Structure Reports Online
    |May 18, 2011
    PubMed
    Summary
    This summary is machine-generated.

    Researchers synthesized sodium erbium bis-(molyb-date), NaEr(MoO(4))(2), a new material with a scheelite structure. This discovery expands the understanding of rare-earth metal molybdate compounds.

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    Area of Science:

    • Solid-state chemistry
    • Materials science
    • Crystallography

    Background:

    • Quaternary systems involving alkali metals (A(1+)), rare-earth metals (RE(3+)), and molybdate (Mo(6+)-O(2-)) are complex.
    • High-temperature solution growth is a key method for synthesizing novel inorganic compounds.

    Purpose of the Study:

    • To explore the A(1+)-RE(3+)-Mo(6+)-O(2-) quaternary systems.
    • To synthesize and characterize a new sodium erbium bis-(molyb-date) compound.

    Main Methods:

    • High-temperature solution growth method.
    • Single-crystal X-ray diffraction for structural determination.

    Main Results:

    • The title compound, sodium erbium bis-(molyb-date), NaEr(MoO(4))(2), was successfully synthesized.
    • The structure is isostructural to scheelite (CaWO(4)).
    • It features [MoO(4)](2-) tetrahedra and statistically mixed Na/Er atoms within [(Na/Er)O(8)](14-) polyhedra (distorted tetragonal anti-prisms).

    Conclusions:

    • The synthesis of NaEr(MoO(4))(2) demonstrates the viability of the high-temperature solution growth method for this class of materials.
    • The structural analysis provides insights into the coordination and bonding within rare-earth metal molybdates.
    • This work contributes to the fundamental understanding of quaternary molybdate systems.