![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Dimethyl cis-4-hydroxy-methyl-piperidine-2,6-dicarboxyl-ate
Jens Hartung1, Georg Stapf, Uwe Bergsträsser
1Fachbereich Chemie, Organische Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern, Germany.
Summary
This study details the crystal structure of a heterocyclic compound, C(10)H(17)NO(5). Its molecular arrangement forms hydrogen-bonded chains and hydrophobic interactions, resulting in a complex three-dimensional crystal lattice.
Area of Science:
- Crystallography
- Organic Chemistry
- Molecular Structure
Background:
- Understanding the three-dimensional arrangement of molecules is crucial in chemistry.
- Heterocyclic compounds play vital roles in various chemical and biological processes.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(10)H(17)NO(5).
- To investigate the intermolecular interactions governing the compound's solid-state architecture.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of hydrogen bonding and hydrophobic interactions was performed.
Main Results:
- The heterocyclic core adopts a chair conformation with equatorial C substituents.
- Intermolecular O-H⋯N hydrogen bonds form chains along the b-axis.
- Hydrophobic interactions and N-H⋯O=C contacts assemble these chains into a 3D structure.
Conclusions:
- The study provides detailed insights into the crystal packing of C(10)H(17)NO(5).
- The observed intermolecular interactions dictate the formation of a robust three-dimensional network.
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