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Updated: Jun 1, 2026

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron
Published on: August 12, 2019
Bis{1,2-bis-[bis-(3-hydroxy-prop-yl)phosphino]ethane}dichloridoiron(II)
Justin L Crossland1, Lev N Zakharov, David R Tyler
1Department of Chemistry, 1253 University of Oregon, Eugene, Oregon 97403-1253, USA.
Abstract:
In the title compound, [FeCl(2)(C(14)H(32)O(4)P(2))(2)], the Fe(II) atom (site symmetry ) adopts a distorted trans-FeCl(2)P(4) octa-hedral geometry with two P,P'-bidentate ligands in the equatorial positions and two chloride ions in the axial positions. In the crystal, mol-ecules are linked by O-H⋯O and O-H⋯Cl hydrogen bonds, generating a three-dimensional network.
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