Related Experiment Video
Updated: Jun 1, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
catena-Poly[[diaqua-manganese(II)]-μ-7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato]
Abstract:
In the title polymer, [Mn(C(8)H(8)O(5))(H(2)O)(2)](n), the Mn(II) atom is in a distorted octa-hedral coordination mode, binding to the bridging O atom of the bicyclo-heptane unit, two O atoms from corresponding carboxyl-ate groups, one carboxyl-ate O atom from a symmetry-related bridging ligand and two water O atoms. This arrangement leads to the formation of polymeric chains propagating parallel to [001]. The crystal structure is stabilized by several O-H⋯O hydrogen-bonding inter-actions involving the coordinated water mol-ecules as donors and the carboxyl-ate O atoms as acceptors.
More Related Videos
05:47Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
09:45Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
Related Concept Videos
Complexometric Titration: Ligands
[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group with both...
Properties of Organometallic Compounds
Complexation Equilibria: The Chelate Effect