![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
{[1-(2-Amino-ethyl-amino)-1-methyl-ethyl]phospho-nato-κN,N',O}chloridopalladium(II) monohydrate
Anatolij Dudko1, Vladimir Bon, Alexandra Kozachkova
1Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, prosp. Palladina 32/34, 03680 Ukraine.
Abstract:
In the title compound, [Pd(C(5)H(14)N(2)O(3)P)Cl]·H(2)O, the Pd(II) atom shows a slightly distorted square-planar geometry and forms two five-membered metallacycles, which both exhibit half-chair conformations. The crystal structure consists of layers propogating in the [100] direction which are connected into a three-dimensional network by strong N-H⋯Cl, N-H⋯O and O-H⋯O hydrogen bonds.
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