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Updated: Jun 1, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-2-[(2-Ethyl-phen-yl)imino-meth-yl]-6-methoxy-phenol
Summary
This study characterizes a novel organic compound, C(16)H(17)NO(2), detailing its phenol-imine tautomerism and crystal structure. The molecule exhibits specific intramolecular hydrogen bonding and intermolecular interactions in its solid state.
Area of Science:
- Organic Chemistry
- Crystallography
- Molecular Structure
Background:
- Understanding tautomerism is crucial in organic chemistry.
- Crystal structure analysis reveals molecular packing and interactions.
- Intramolecular hydrogen bonds influence molecular conformation and properties.
Purpose of the Study:
- To elucidate the tautomeric form of the title compound.
- To determine the crystal structure and intermolecular interactions.
- To analyze the conformation and bonding characteristics.
Main Methods:
- Single-crystal X-ray diffraction was employed.
- Analysis of bond lengths, angles, and dihedral angles.
- Identification of hydrogen bonding and other intermolecular forces.
Main Results:
- The compound exists in the phenol-imine tautomeric form.
- A strong intramolecular O-H⋯N hydrogen bond was observed.
- The molecule adopts an E conformation around the azomethine bond.
- The dihedral angle between aromatic rings is 21.23°.
- The ethyl group shows positional disorder.
- Molecules form chains via C-H⋯π interactions in the crystal.
Conclusions:
- The study provides a detailed structural characterization of the title compound.
- The observed structural features, including tautomerism and hydrogen bonding, are significant.
- The crystal packing reveals specific intermolecular interactions influencing the solid-state structure.
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