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Updated: Jun 1, 2026

Continuous Flow Chemistry: Reaction of Diphenyldiazomethane with p-Nitrobenzoic Acid
Published on: November 15, 2017
2,2'-(4-Amino-4H-1,2,4-triazole-3,5-di-yl)diphenol
Sheng-Hui Chen1, Gao-Yong Zhang, Jin-Feng Dong
1College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, People's Republic of China.
Abstract:
The structure of the title compound, C(14)H(12)N(4)O(2), was determined as part of a project on the coordination chemistry of 1,2,4-triazole derivatives. In the crystal structure, one of the two benzene rings is almost coplanar with the five-membered triazole ring (mean deviation = 0.019 Å), whereas the second benzene ring is rotated by 51.973 (2)°. The two N-C-N-N torsion angles [170.365 (2) and -170.942 (3)°] indicate that the amido group is slightly twisted away from the triazole plane. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal structure, inter-molecular N-H⋯O and O-H⋯N hydrogen bonding is found.
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