Related Experiment Video

Updated: Jun 1, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
11:45

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

4-(Methyl-sulfon-yl)piperazin-1-ium chloride

Hoong-Kun Fun, Chin Sing Yeap, C S Chidan Kumar

    Acta Crystallographica. Section E, Structure Reports Online
    |May 18, 2011
    PubMed

    Abstract:

    In the title mol-ecular salt, C(5)H(13)N(2)O(2)S(+)·Cl(-), the complete cation is generated by crystallographic mirror symmetry, with both N atoms, the S atom and one C atom lying on the reflecting plane. The chloride ion also lies on the mirror plane. The piperazinium ring adopts a chair conformation and the N-S bond adopts an equatorial orientation. In the crystal structure, the component ions are linked into a three-dimensional framework by inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds.

    More Related Videos

    Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
    11:44

    Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

    Published on: March 20, 2014

    Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
    19:58

    Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

    Published on: July 30, 2017

    Related Experiment Videos

    Last Updated: Jun 1, 2026

    Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
    11:45

    Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

    Published on: August 22, 2018

    Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
    11:44

    Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

    Published on: March 20, 2014

    Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
    19:58

    Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

    Published on: July 30, 2017

    Related Concept Videos

    Alkyl Halides02:45

    Alkyl Halides

    Structural Properties
    Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
    Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
    Chirality at Nitrogen, Phosphorus, and Sulfur02:30

    Chirality at Nitrogen, Phosphorus, and Sulfur

    Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
    A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...

    Articles linked to this work by shared authors, journal, and citation graph.

    Rapid and sensitive electrochemical detection of paracetamol using EuZrO3-modified carbon paste electrode.

    Scientific reports·2025

    Solvent effect, DFT and NLO studies of A-π-D-π-A and A-π-D-π-D push-pull chromophore of 1,2-diazepin-4-ol based derivatives with optical limiting application.

    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2024

    Enhanced NLO response and switching self-focussing in benzodiazepine derivative with -NO2 and -Br substitution.

    Heliyon·2023

    Quantum chemical calculation, performance of selective antimicrobial activity using molecular docking analysis, RDG and experimental (FT-IR, FT-Raman) investigation of 4-[{2-[3-(4-chlorophenyl)-5-(4-propan-2-yl) phenyl)-4, 5-dihydro- 1H- pyrazol-1-yl]-4-oxo-1, 3- thiazol-5(4H)-ylidene} methyl] benzonitrile.

    Heliyon·2021

    Understanding reactivity of a triazole derivative and its interaction with graphene and doped/undoped-coronene-a DFT study.

    Journal of biomolecular structure & dynamics·2020

    Experimental database on water equivalent factor (WEQp) and organically bound tritium activity for tropical monsoonal climate region of South West Coast of India.

    Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine·2020

    Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of methyl 1-methyl-3,5-diphenyl-7-tosyl-3,6,7,11b-tetra-hydro-pyrazolo-[4',3':5,6]pyrano[3,4-c]quinoline-5a(5H)-carboxyl-ate.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of 4-amino-1-(4-methyl-benz-yl)pyridinium bromide.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of (Z)-3-benz-yloxy-6-[(2-hy-droxy-anilino)methyl-idene]cyclo-hexa-2,4-dien-1-one.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of bis-(1-benzyl-1H-1,2,4-triazole) perchloric acid monosolvate.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.

    Acta crystallographica. Section E, Structure reports online·2015

    Base-promoted dearomatization/1,6-addition of α-haloketones: synthesis of α-azido-α,α-diaryl ketones.

    Chemical communications (Cambridge, England)·2026

    Enantioselective Access to Trifluoromethylated Spirocyclopropyl Heterocycles.

    Advanced science (Weinheim, Baden-Wurttemberg, Germany)·2026

    Organocatalytic Enantioselective Electrophilic C-H Sulfenylation of Arenes.

    Accounts of chemical research·2026

    Palladium-Catalyzed Fluoroallylation of Aldimine Esters With gem-Difluorocyclopropanes: Synthesis of Fluorinated α-Amino Acid Derivatives.

    Chemistry, an Asian journal·2026

    Correction: Imine-anion-mediated alkoxy-group-elimination-type SNAr reaction: an efficient synthetic route to phenanthridines.

    Chemical communications (Cambridge, England)·2026

    Mechanochemical three-component radical sulfonamidation enabled by copper catalysis.

    Chemical communications (Cambridge, England)·2026
    See all related articles
    JoVE
    x logofacebook logolinkedin logoyoutube logo
    ABOUT JoVE
    OverviewLeadershipBlogJoVE Help Center
    AUTHORS
    Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
    LIBRARIANS
    TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
    RESEARCH
    JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
    EDUCATION
    JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
    Terms & Conditions of Use
    Privacy Policy
    Policies
    Jove
    Visualize
    Contact Us