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Updated: Jun 1, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Aqua-chlorido{μ-6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}copper(II)sodium(I)
1School of Chemistry & Chemical Technology, Shandong University, Jinan 250100, People's Republic of China.
Abstract:
In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord-inated in a square-planar geometry by two N atoms and two O atoms of the 6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl--idyne)]diphenolate ligand. The Na(I) ion is hexa-coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol-ecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms.
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