Related Experiment Video
Updated: Jun 1, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
09:12
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Bis{μ-1-[(2-oxidophen-yl)imino-meth-yl]-2-naphtholato}bis-[pyridine-copper(II)]
Kai Liu1, Guihua Liu, Zhiqiang Cao
1College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Abstract:
The dinuclear title complex, [Cu(2)(C(17)H(11)NO(2))(2)(C(5)H(5)N)(2)], consists of centrosymmetric dimers in which the Cu(II) atom displays an elongated square-pyramidal coordination geometry. The conformation of the dimer is stabilized by inter-molecular C-H⋯O hydrogen bonds and by π-π aromatic stacking inter-actions involving the pyridine and benzene rings with centroid-centroid separations of 3.624 (3) Å.
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)