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Updated: Jun 1, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
N-(3-Bromo-5-methyl-2-pyrid-yl)-4-methyl-benzene-sulfonamide
Ming Peng1, Youfu Luo, Lijuan Chen
1State Key Laboratory of Biotherapy, Sichuan University, Chengdu 610064, People's Republic of China.
Abstract:
In the mol-ecule of the title compound, C(13)H(13)BrN(2)O(2)S, the dihedral angle formed by the pyridine and benzene rings is 66.87 (3)°. An intra-molecular N-H⋯Br hydrogen bond is observed. In the crystal structure, N-H⋯O hydrogen bonds, C-H⋯π inter-actions and aromatic π-π stacking inter-actions [centroid-centroid distance = 3.757 (14) Å] link the mol-ecules into a three-dimensional network.
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