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Updated: Jun 1, 2026
Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
(Acetato-κO)(2,2'-bipyridine-κN,N')trimethyl-platinum(IV) monohydrate
Cornelia Vetter1, Christoph Wagner, Dirk Steinborn
1Anorganische Chemie, Institut für Chemie, Martin-Luther-Universität, Kurt-Mothes-Strasse 2, Halle-Wittenberg, D-06120 Halle, Germany.
Abstract:
In the title hydrate, [Pt(CH(3))(3)(CH(3)COO)(C(10)H(8)N(2))]·H(2)O, the Pt(IV) atom exhibits a distorted octa-hedral coordination geometry built up by three methyl ligands in a facial arrangement, a bipyridine ligand and a monodentately bound acetate ligand. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds are observed between the water mol-ecule and the platinum complex, which link the mol-ecules into chains along the c axis.
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