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{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate

Christoph E Strasser1, Jimmy E Y Sumani, Helgard G Raubenheimer

  • 1Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland, 7602, South Africa.

Acta Crystallographica. Section E, Structure Reports Online
|May 18, 2011
PubMed

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Diazonium Group Substitution: –OH and –H01:19

Diazonium Group Substitution: –OH and –H

Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.