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Updated: Jun 1, 2026
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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
Published on: October 30, 2018
1-(3-Mesityl-3-methyl-cyclo-butyl)-2-phenoxy-ethanone
Summary
This study details the crystal structure of a compound, revealing a puckered cyclobutane ring. Intermolecular interactions were observed between the cyclobutyl group and the phenoxy oxygen atom.
Area of Science:
- Organic Chemistry
- Crystallography
Background:
- Understanding molecular structure and intermolecular forces is crucial in organic chemistry.
- Crystal structure analysis provides detailed insights into molecular arrangement and interactions.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(22)H(26)O(2).
- To identify and characterize intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and dihedral angles provided structural details.
- Identification of non-classical hydrogen bonds was performed.
Main Results:
- The cyclobutane ring in the title compound exhibits a puckered conformation.
- A significant dihedral angle of 24.97(9)° was measured between the two C(3) planes of the cyclobutane ring.
- Intermolecular non-classical C-H⋯O interactions were identified between the methyl-cyclobutyl group and the phenoxy oxygen atom.
Conclusions:
- The study provides a detailed structural characterization of the title compound.
- The observed puckered cyclobutane ring conformation and specific intermolecular interactions offer insights into the compound's solid-state behavior.
- These findings contribute to the understanding of structure-property relationships in organic molecules.
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