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Updated: Jun 1, 2026

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
Poly[tetra-aqua-(μ(4)-benzene-1,3,5-tri-carboxyl-ato)sodium(I)zinc(II)]
Chao-Hong Ma1, Xiu-Yan Wang, Xian-Wu Dong
1Jilin Agricultural Science and Technology College, Jilin 132101, People's Republic of China.
Abstract:
In the title compound, [NaZn(C(9)H(3)O(6))(H(2)O)(4)](n), the Zn(II) atom is six-coordinated by four O atoms from two different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted tetragonal-bipyramidal geometry and the Na(I) atom is five-coordinated by three O atoms from three different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted trigonal-bipyramidal geometry. The benzene-1,3,5-tricarboxyl-ate anion bridges two Zn(II) atoms and two Na(I) atoms, resulting in the formation of a two-dimensional layer structure. Inter-molecular O-H⋯O hydrogen-bonding inter-actions generate a three-dimensional superamolecular structure.
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