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Updated: Jun 1, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate
Nozipho M Khumalo1, Reinout Meijboom, Alfred Muller
1Synthesis and Catalysis Research Centre, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.
Abstract:
In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C-H⋯π inter-actions.
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