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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
(2E)-3-(2-Chloro-6-methyl-3-quinol-yl)-1-(1-naphth-yl)prop-2-en-1-one
Abstract:
In the title mol-ecule, C(23)H(16)ClNO, the quinoline and naphthalene ring systems are individually planar, with maximum deviations of 0.020 (2) and 0.033 (2) Å, respectively, and are inclined at a dihedral angle of 30.01 (4)°. Intra-molecular C-H⋯O and C-H⋯Cl inter-actions occur. The crystal structure is devoid of any classical hydrogen bonds, but symmetry-related mol-ecules are linked via weak C-H⋯Cl inter-actions, forming chains propagating in [001].
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