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Updated: Jun 1, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-N'-(2,5-Dimethoxy-benzyl-idene)-2,4-dihydroxy-benzohydrazide.
Jing-Yuan Wei1, De-Guang Song, Da-Cheng Wang
1College of Animal Science and Veterinary Medicine, Jilin University, Changchun 130062, People's Republic of China.
Summary
This study details the crystal structure of a novel organic compound, C(16)H(16)N(2)O(5). Molecular analysis reveals specific dihedral angles and hydrogen bonding patterns influencing its layered crystal structure.
Area of Science:
- Crystallography
- Organic Chemistry
- Materials Science
Background:
- Understanding molecular interactions is crucial for designing new materials.
- Hydrogen bonding plays a significant role in crystal packing and material properties.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(16)H(16)N(2)O(5).
- To investigate the intermolecular and intramolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and hydrogen bonding networks was performed.
Main Results:
- The crystal structure of C(16)H(16)N(2)O(5) was determined, revealing a dihedral angle of 4.2(2)° between the two benzene rings.
- An intramolecular O-H⋯O hydrogen bond was identified, forming an S(6) ring.
- Molecules are arranged in layers parallel to the bc plane through O-H⋯O and N-H⋯O intermolecular hydrogen bonds.
Conclusions:
- The specific arrangement of molecules in the crystal lattice is dictated by a combination of intramolecular and intermolecular hydrogen bonding.
- The observed hydrogen bonding network influences the overall layered structure of the compound.
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