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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron
Published on: August 12, 2019
(2,3,7,8,12,13,17,18-Octa-ethyl-por-phin-ato)(trifluoro-methane-sulfonato)iron(III)
Nan Xu1, Douglas R Powell, George B Richter-Addo
1Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA.
Abstract:
The title compound, [Fe(CF(3)O(3)S)(C(36)H(44)N(4))], is an iron(III) porphyrin complex with the trifluoro-methane-sulfonate anion as an axial ligand. The Fe atom is displaced by 0.219 (2) Å toward the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin, resulting in a distorted FeN(4)O square-based pyramidal geometry. One ethyl-ene group is disordered over two orientations in a 0.502 (6):0.498 (6) ratio.
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