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Updated: Jun 1, 2026
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
4-(Cyclo-hexyl-sulfan-yl)-1-[(E)-2-(cyclo-hexyl-sulfan-yl)-1-phenyl-ethen-yl]-3-phenyl-1H-pyrazole
Abstract:
In the title compound, C(29)H(34)N(2)S(2), the pyrazole ring is planar and both cyclo-hexane rings adopt chair conformations. The dihedral angles between the pyrazole ring and the two benzene rings are 59.9 (2) and 19.8 (2)°. The conformation and packing of the mol-ecules in the unit cell are stabilized by a weak intra-molecular C-H⋯S and C-H⋯N interactions, in addition to van der Waals forces.
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