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(2RS,8aRS)-6-Oxo-1,2,3,4,6,7,8,8a-octa-hydro-naphthalene-2-carboxylic acid
Georgia Efthimiopoulos1, Roger A Lalancette, Hugh W Thompson
1Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, Newark, NJ 07102, USA.
Abstract:
The title racemate, C(11)H(14)O(3), aggregates in the crystal structure as acid-to-ketone O-H⋯O hydrogen-bonding catemers whose components are glide-related. The relative stereochemistry at the carboxyl group arises spontaneously during the synthesis. Two inter-molecular C-H⋯O=C close contacts were found, both involving the acid group.
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