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Updated: Jun 1, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-2-(5,5-Dimethyl-hexa-hydro-pyrimidin-2-yl)-4-(phenyl-diazen-yl)phenol
Abstract:
In the title Schiff base, C(18)H(22)N(4)O, the hexa-hydro-pyrimidinyl ring adopts a chair conformation. The dihedral angle between the aromatic rings of the 4-(2-phenyl-diazen-yl)phenol unit is 15.7 (1)°. There is an intra-molecular O-H⋯N hydrogen bond between the hydroxyl group and an N atom of the hexa-hydro-pyimidinyl unit. Inter-molecular N-H⋯O and N-H⋯N hydrogen bonds give rise to a layer structure.
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