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Updated: Dec 17, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
3,3'-Dimethyl-1,1'-(propane-1,3-di-yl)diimidazol-1-ium bis(hexafluoro-phosphate)
Abstract:
In the title compound, C(11)H(18)N(4) (2+)·2PF(6) (-), the dihedral angle between the two planar imidozlium rings is 6.1 (2)°. Both [PF(6)](-) anions are disordered [occupancies 0.65 (2):0.35 (2) and 0.59 (5):0.41 (5)]. The crystal packing is stabilized by inter-molecular C-H⋯F hydrogen bonds which link two mol-ecules, forming centrosymmetric dimers.
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