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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Aquabis-(6-bromo-picolinato-κN,O)copper(II).
Fei-Long Hu1, Zhuang Yue, Mi Yan
1College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.
Summary
This study details the crystal structure of a copper compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], revealing a distorted trigonal-bipyramidal coordination. Hydrogen bonds form chains within the crystal structure.
Area of Science:
- Inorganic Chemistry
- Crystallography
- Coordination Chemistry
Background:
- Copper complexes are vital in catalysis and materials science.
- Understanding coordination geometries is key to predicting chemical properties.
Purpose of the Study:
- To elucidate the coordination environment and crystal structure of a novel copper(II) complex.
- To analyze the intermolecular interactions governing crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Coordination geometry and hydrogen bonding interactions were analyzed.
Main Results:
- The copper(II) center exhibits a distorted trigonal-bipyramidal coordination geometry.
- Two N,O-bidentate ligands and a water molecule coordinate to the copper atom.
- The dihedral angle between the pyridine rings is 67.6°.
- O-H⋯O hydrogen bonds link molecules into chains propagating along the [100] direction.
Conclusions:
- The study provides detailed structural insights into copper coordination complexes.
- The observed hydrogen bonding network influences the solid-state architecture.
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