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Updated: Jun 1, 2026
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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
trans-Dichlorido-bis(3,4-dimethyl-pyridine)platinum(II)
Summary
This study details the crystal structure of trans-[PtCl(2)(C(7)H(9)N)(2)], a platinum(II) compound with a distorted square-planar geometry. The inversion center dictates a linear torsion angle and coplanar dimethyl-pyridine ligands.
Area of Science:
- Inorganic Chemistry
- Crystallography
- Coordination Chemistry
Background:
- Platinum(II) complexes are crucial in catalysis and medicine.
- Understanding the precise geometry of these complexes informs their reactivity.
- Structural studies reveal fundamental bonding and packing principles.
Purpose of the Study:
- To elucidate the detailed crystal structure of trans-[PtCl(2)(C(7)H(9)N)(2)].
- To analyze the coordination geometry and ligand arrangement around the platinum(II) center.
- To investigate the influence of the inversion center on molecular conformation.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Crystallographic data were analyzed to establish bond lengths, angles, and torsion angles.
- The coordination environment of the platinum(II) ion was characterized.
Main Results:
- The compound exhibits a trans configuration with a slightly distorted square-planar geometry around the Pt(II) atom.
- The platinum(II) center lies on a crystallographic inversion center.
- Two 3,4-dimethyl-pyridine ligands and two chloride ligands coordinate the platinum(II) ion.
- The inversion center enforces a linear C-N-N-C torsion angle and coplanar dimethyl-pyridine ligands.
Conclusions:
- The crystal structure of trans-[PtCl(2)(C(7)H(9)N)(2)] is fully determined.
- The molecular geometry is dictated by the presence of the inversion center, leading to specific ligand orientations.
- This structural insight contributes to the understanding of platinum coordination complexes.
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
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