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Updated: Jun 1, 2026

Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Published on: April 27, 2017
1-(2,6-Dichloro-benzo-yl)-3-(3-methoxy-phen-yl)thio-urea
Abstract:
The two aromatic rings in the title compound, C(15)H(12)Cl(2)N(2)O(2)S, enclose a dihedral angle of 37.49 (6)°. The mol-ecule exists in the solid state in its thione form with typical thio-urea C-S and C-O bonds lengths, as well as shortened C-N bonds. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation. In the crystal, mol-ecules are connected by N-H⋯O and N-H⋯S hydrogen bonds, forming chains running along the a axis.
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