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Updated: Jun 1, 2026

Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Published on: April 27, 2017
Poly[[[diisothio-cyanato-cobalt(II)]-bis-[μ-4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol]]
1Institute of Molecular Engineering & Applied Chemistry, School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, People's Republic of China.
Abstract:
In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104 (3)-2.144 (3) Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl-formamide and solvent water mol-ecules participate in inter-molecular O-H⋯O and O-H⋯S hydrogen bonds, which consolidate the crystal packing.
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