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Updated: Jun 1, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
N,N-Dimethyl-4-[(E)-phenyl-imino-meth-yl]aniline.
Lei Zheng1, Xiu-Juan Yin, Cong-Ling Yang
1College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China.
This study details the molecular structure of a C(15)H(16)N(2) compound, revealing two aromatic rings connected by an imino group. The molecule features an E configuration around the C=N bond and a specific dihedral angle between the rings.
Area of Science:
- Organic Chemistry
- Crystallography
- Molecular Structure
Background:
- The synthesis and structural characterization of organic compounds are fundamental to advancing chemical science.
- Aromatic compounds and imines represent important classes of molecules with diverse applications.
Purpose of the Study:
- To elucidate the precise three-dimensional molecular structure of the title compound, C(15)H(16)N(2).
- To determine the stereochemistry and conformational properties of the molecule, specifically the configuration of the imino group and the inter-ring dihedral angle.
Main Methods:
- Single-crystal X-ray diffraction was employed to obtain detailed structural data.
- Analysis of the diffraction data allowed for the determination of bond lengths, bond angles, and torsion angles.
Main Results:
- The title compound, C(15)H(16)N(2), was structurally characterized.
- The molecule possesses two aromatic rings linked by an imino group (C=N).
- The compound exhibits an E configuration about the C=N double bond, with a dihedral angle of 61.96° between the aromatic rings.
Conclusions:
- The study provides a definitive structural description of the C(15)H(16)N(2) compound.
- The determined E configuration and dihedral angle offer insights into the molecule's conformation and potential intermolecular interactions.
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