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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
1,5-Bis(4-chloro-phen-yl)-3-[4-(dimethyl-amino)phen-yl]pentane-1,5-dione
1College of Life Sciences and Chemistry, Tianshui Normal University, Tianshui 741000, People's Republic of China.
Abstract:
In the title mol-ecule, C(25)H(23)Cl(2)NO(2), the central benzene ring forms dihedral angles of 81.88 (7) and 89.22 (7)° with the two 4-chloro-phenyl fragments. The crystal packing exhibits weak inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance 3.724 (3) Å].
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