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Updated: Jun 1, 2026
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
3,4,5-Trimethyl-2,4,6-triphenyl-4H-thio-pyran
Abstract:
The six-membered thio-pyran ring in the title compound, C(26)H(24)S, adopts a boat conformation, with the S atom displaced by 0.478 (2) Å and the 3-methyl-ene C atom by 0.644 (2) Å from the plane of the other four sp(2)-hydridized C atoms. The methyl group on the methyl-ene carbon lies in a pseudo-equatorial position and the phenyl ring in a pseudo-axial position.
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