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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
1-(4-Chloro-phen-yl)-4,4-dimethyl-pent-1-en-3-one
Tian-Quan Wu1, Lin Xia, Ai-Xi Hu
1College of Chemistry and Chemical Engineering, Hunan University 410082, Changsha, People's Republic of China.
Abstract:
In the title compound, C(13)H(15)ClO, the carbonyl and ethenyl groups are not coplanar with benzene ring system, forming dihedral angles of 35.37 (5) and 36.27 (11)°, respectively. The mol-ecules are packed in an offset face-to-face arrangement showing π-π stacking inter-actions involving the benzene rings [centroid-centroid distance = 3.586 (4) Å].
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