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Bis[μ-N'-isobutyryl-1-oxidonaphtha-lene-2-carbohydrazidato(3-)]dipyridine-tricopper(II)

Xue-Feng Shi1, Dacheng Li, Pi-Yong Li

  • 1College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online
|May 18, 2011
PubMed

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group with both...